ZHENG Binxing, LV Diya, FANG Fang, LIU Yanhua, LI Dan, LU Feng, XU Jiyang. Detection of malachite green in natural indigo by surface enhanced Raman spectroscopy based on monolithic column[J]. Journal of Pharmaceutical Practice and Service, 2015, 33(5): 426-428,459. doi: 10.3969/j.issn.1006-0111.2015.05.011
Citation:
|
ZHENG Binxing, LV Diya, FANG Fang, LIU Yanhua, LI Dan, LU Feng, XU Jiyang. Detection of malachite green in natural indigo by surface enhanced Raman spectroscopy based on monolithic column[J]. Journal of Pharmaceutical Practice and Service, 2015, 33(5): 426-428,459. doi: 10.3969/j.issn.1006-0111.2015.05.011
|
Detection of malachite green in natural indigo by surface enhanced Raman spectroscopy based on monolithic column
- 1.
School of Life Science and Technology, China Pharmaceutical University, Nanjing 210009, China
- 2.
School of Pharmacy, the Second Military Medical University, Shanghai 200433, China
- 3.
School of Pharmacy, Fujian University of Traditional Chinese Medicine, Fuzhou 350108, China
- Received Date: 2015-02-09
- Rev Recd Date:
2015-05-28
-
Abstract
Objective To develop a rapid SERS detection method based on monolithic column for detection of dye adulterated natural indigo. Methods The dyes in natural indigo were extracted and mixed with silver colloid. The spectra were recorded after applying the mixture solution to the monolithic column since the intertwined pores in monolithic column could contribute for the distribution of silver nanoparticles. Results SERS signals of malachite green dyed natural indigo at quantity as low as 500 μg/kg could be obtained. Conclusion This simple,fast and specific SERS detection method based on monolithic column could be used for rapid detection of stained natural indigo.
-
References
[1]
|
吴云燕, 孙雪妮. 中药饮片染色现象不容忽视[J]. 中草药, 2001, 32(8): 752-753. |
[2]
|
姚志昂. 青黛的质量考察与掺伪研究[D]. 成都: 成都中医药大学, 2011. |
[3]
|
蒋 玲, 饶伟文. 中药染色掺假的研究进展[J]. 首都医药, 2011, 18(16): 16-18. |
[4]
|
谢云飞, 李 言, 余 慧, 等. 整体柱-金复合基底的制备及其在色素 SERS 检测的应用[J]. 光谱学与光谱分析, 2014, 34(3): 681-684. |
[5]
|
Kubackova J, Fabriciova G, Miskovsky P, et al. Sensitive surface-enhanced Raman spectroscopy (SERS) detection of organochlorine pesticides by alkyl dithiol-functionalized metal nanoparticles-induced plasmonic hot spots[J]. Anal Chem, 2015, 87(1): 663-669. |
[6]
|
渠陆陆, 李大伟, 翟文磊, 等. 基于表面增强拉曼光谱的水中芳香胺类污染物现场快速检测技术[J]. 环境化学, 2011, 30(8): 1486-1492. |
[7]
|
樊玉霞, 赖克强, 黄轶群. 表面增强拉曼光谱技术在食品痕量化学危害检测中的应用[J]. 光谱学与光谱分析, 2014, 34(7): 1859-1864. |
[8]
|
Li Q, Du Y, Tang H, et al. Ultra sensitive surface-enhanced Raman scattering detection based on monolithic column as a new type substrate[J]. J Raman Spectrosc, 2012, 43(10): 1392-1396. |
[9]
|
Svec F, Fréchet JMJ. Continuous rods of macroporous polymer as high-performance liquid chromatography separation media[J]. Anal Chem, 1992, 64(7): 820-822. |
[10]
|
Lee PC, Meisel D. Adsorption and surface-enhanced Raman of dyes on silver and gold sols[J]. J Phys Chem, 1982, 86(17): 3391-3395. |
[11]
|
Zhu Q, Cao Y, Cao Y, et al. Rapid on-site TLC-SERS detection of four antidiabetes drugs used as adulterants in botanical dietary supplements[J]. Anal Bioanal Chem, 2014, 406(7): 1877-1884. |
-
-
Proportional views
-